R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine
CAS: 158923-09-2
Molecular Formula: C36H44FeP210*
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine - Names and Identifiers
| Name | R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine |
| Synonyms | (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-phenylphosphine (R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE |
| CAS | 158923-09-2 |
| InChI | InChI=1/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h2-3,6-9,14-18,23-25,28-29H,4-5,10-13,19-22H2,1H3;1-5H;/t25-;;/m1../s1 |
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine - Physico-chemical Properties
| Molecular Formula | C36H44FeP210* |
| Molar Mass | 594.53 |
| Specific Rotation(α) | -100° ±5° (c 0.5, CHCl3) |
| Appearance | Powder |
| Color | orange |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10 |
| HS Code | 29319090 |
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine - Introduction
R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine (abbreviated FpPPh2) is an organic compound with the following properties:
1. Appearance: FpPPh2 is a yellow crystal or powder substance.
2. Melting Point: the melting point of FpPPh2 is between 160-170 ℃.
3. Solubility: FpPPh2 has good solubility in common organic solvents.
4. Stability: FpPPh2 is stable in regular air, but it is oxidizing at high temperature and in the presence of oxygen.
The purpose of FpPPh2:
FpPPh2 is an important ligand used in organometallic chemistry research. It is widely used in transition metal catalysis, coordination chemistry and organic synthesis reactions. For example, it can be used as a chiral ligand and catalyst to participate in asymmetric catalytic reactions to synthesize chiral molecules. In addition, FpPPh2 can also be used in electrochemical studies and as a precursor for metal catalysts.
FpPPh2 preparation method:
FpPPh2 can be prepared by the reaction of a ferrocenyl compound and a p-diphenylphosphinomethyl compound. The specific preparation method may vary depending on the experimental conditions.
Safety information for FpPPh2:
FpPPh2 is safer for humans and the environment under normal operating conditions, but it is still recommended to take appropriate personal protective measures during operation, such as wearing gloves and goggles. In addition, it should be stored in a dry, cool place, and away from fire and oxidizing agents. For specific safe practice guidelines and waste disposal methods, reference should be made to the safety data sheets and technical instructions provided by the chemical supplier.
1. Appearance: FpPPh2 is a yellow crystal or powder substance.
2. Melting Point: the melting point of FpPPh2 is between 160-170 ℃.
3. Solubility: FpPPh2 has good solubility in common organic solvents.
4. Stability: FpPPh2 is stable in regular air, but it is oxidizing at high temperature and in the presence of oxygen.
The purpose of FpPPh2:
FpPPh2 is an important ligand used in organometallic chemistry research. It is widely used in transition metal catalysis, coordination chemistry and organic synthesis reactions. For example, it can be used as a chiral ligand and catalyst to participate in asymmetric catalytic reactions to synthesize chiral molecules. In addition, FpPPh2 can also be used in electrochemical studies and as a precursor for metal catalysts.
FpPPh2 preparation method:
FpPPh2 can be prepared by the reaction of a ferrocenyl compound and a p-diphenylphosphinomethyl compound. The specific preparation method may vary depending on the experimental conditions.
Safety information for FpPPh2:
FpPPh2 is safer for humans and the environment under normal operating conditions, but it is still recommended to take appropriate personal protective measures during operation, such as wearing gloves and goggles. In addition, it should be stored in a dry, cool place, and away from fire and oxidizing agents. For specific safe practice guidelines and waste disposal methods, reference should be made to the safety data sheets and technical instructions provided by the chemical supplier.
Last Update：2024-04-09 20:52:54
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